Propan-1-aminium 3,4,5,6-tetrachloro-2-(methoxycarbonyl)benzoate
نویسنده
چکیده
In the anion of the title salt, C(3)H(10)N(+)·C(9)H(3)Cl(4)O(4) (-), the meth-oxy-carbonyl and carboxyl groups are aligned at dihedral angles of 57.8 (3) and 62.5 (3)°, respectively, with the aromatic ring. In the crystal, the cations and anions are linked by N-H⋯O hydrogen bonds, generating chains running aong the c axis.
منابع مشابه
Propan-1-aminium 3,4,5,6-tetrabromo-2-(methoxycarbonyl)benzoate N,N-dimethylformamide monosolvate
In the anion of the title solvated molecular salt, C(3)H(10)N(+)·C(9)H(3)Br(4)O(4) (-)·C(3)H(7)NO, the dihedral angles formed by the aromatic ring and the mean planes of the carboxyl-ate and meth-oxy-carbonyl groups are 64.3 (3) and 75.2 (3)°, respectively. The C atoms of the propan-1-aminium cation are disordered over two sets of sites in a 0.65 (3):0.35 (3) ratio. The crystal structure is sta...
متن کاملMethanaminium 3,4,5,6-tetrachloro-2-(methoxycarbonyl)benzoate
In the crystal structure of the title compound, CH(6)N(+)·C(9)H(3)Cl(4)O(4) (-), the N atom of the methyl-amine mol-ecule is protonated and hydrogen bonded to the carboxyl group of the 3,4,5,6-tetra-chloro-2-(meth-oxy-carbon-yl)benzoate anion. The anions are linked by the cations via inter-molecular N-H⋯O inter-actions into chains extending along the c axis.
متن کاملButane-1,4-diaminium bis[3,4,5,6-tetrachloro-2-(methoxycarbonyl)benzoate]
In the title salt, C(4)H(14)N(2) (+)·2C(9)H(3)Cl(4)O(4) (-), the cation lies on an inversion center. In the anion, the mean planes of meth-oxy-carbonyl and carboxyl-ate groups form dihedral angles of 64.9 (3) and 58.5 (3)°, respectively, with the benzene ring. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the components into sheets parallel to (100).
متن کاملHexane-1,6-diaminium bis[3,4,5,6-tetrachloro-2-(methoxycarbonyl)benzoate]
In the anion of the title salt, C(6)H(18)N(2) (2+)·2C(9)H(3)Cl(4)O(4) (-), the meth-oxy-carbonyl and carboxyl groups are aligned at dihedral angles of 71.0 (3) and 100.9 (3)°, respectively, with the aromatic ring. The asymmetric unit contains half a cation and one anion. In the crystal, inter-molecular N-H⋯O, C-H⋯Cl and C-H⋯O hydrogen bonds link the components into a three-dimensional network.
متن کامل2-Methylpropan-2-aminium 3,4,5,6-tetrabromo-2-(methoxycarbonyl)benzoate methanol monosolvate
In the crystal structure of the title compound, C(4)H(12)N(+)·C(9)H(3)Br(4)O(4) (-)·CH(4)O, inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds link the components into columns stacked along the b axis. Between the columns, short Br⋯O contacts [3.122 (4) Å] and C-H⋯O hydrogen bonds are observed.
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